1ES 1959+650 is one of the most remarkable high-peaked BL Lacertae objects ( HBL ) . In 2002 it exhibited a TeV \gamma –ray flare without a similar brightening of the synchrotron component at lower energies . This orphan TeV flare remained a mystery . We present the results of a multifrequency campaign , triggered by the INTEGRAL IBIS detection of 1ES 1959+650 . Our data range from the optical to hard X-ray energies , thus covering the synchrotron and inverse-Compton components simultaneously . We observed the source with INTEGRAL , Swift /XRT , and UV-Optical Telescope , and nearly simultaneously with ground-based optical telescope . The steep spectral component at X-ray energies is most likely due to synchrotron emission , while at soft \gamma -ray energies the hard spectral index may be interpreted as the onset of the high-energy component of the blazar spectral energy distribution ( SED ) . This is the first clear measurement of a concave X-ray – soft \gamma -ray spectrum for an HBL . The SED can be well modeled with a leptonic synchrotron- self-Compton model . When the SED is fitted this model requires a very hard electron spectral index of q \sim 1.85 , possibly indicating the relevance of second-order Fermi acceleration .