Context : One of the open questions in astrochemistry is how complex organic and prebiotic molecules are formed .
The unsurpassed sensitivity of the Atacama Large Millimeter/submillimeter Array ( ALMA ) takes the quest for discovering molecules in the warm and dense gas surrounding young stars to the next level .

Aims : Our aim is to start the process of compiling an inventory of oxygen-bearing complex organic molecules toward the solar-type Class 0 protostellar binary IRAS 16293-2422 from an unbiased spectral survey with ALMA , Protostellar Interferometric Line Survey ( PILS ) .
Here we focus on the new detections of ethylene oxide ( c-C _ { 2 } H _ { 4 } O ) , acetone ( CH _ { 3 } COCH _ { 3 } ) , and propanal ( C _ { 2 } H _ { 5 } CHO ) .

Methods : With ALMA , we surveyed the spectral range from 329 to 363 GHz at 0.5 ^ { \prime \prime } ( 60 AU diameter ) resolution .
Using a simple model for the molecular emission in local thermodynamical equilibrium , the excitation temperatures and column densities of each species were constrained .

Results : We successfully detect propanal ( 44 lines ) , ethylene oxide ( 20 lines ) and acetone ( 186 lines ) toward one component of the protostellar binary , IRAS16293B .
The high resolution maps demonstrate that the emission for all investigated species originates from the compact central region close to the protostar .
This , along with a derived common excitation temperature of T _ { \mathrm { ex } } \approx 125 K , is consistent with a coexistence of these molecules in the same gas .

Conclusions : The observations mark the first detections of acetone , propanal and ethylene oxide toward a low-mass protostar .
The relative abundance ratios of the two sets of isomers , a CH _ { 3 } COCH _ { 3 } /C _ { 2 } H _ { 5 } CHO ratio of 8 and a CH _ { 3 } CHO/c-C _ { 2 } H _ { 4 } O ratio of 12 , are comparable to previous observations toward high-mass protostars .
The majority of observed abundance ratios from these results as well as those measured toward high-mass protostars are up to an order of magnitude above the predictions from chemical models .
This may reflect either missing reactions or uncertain rates in the chemical networks .
The physical conditions , such as temperatures or densities , used in the models , may not be applicable to solar-type protostars either .