Following a previous paper on Thomson scattering , we present numerical simulations of the periodic polarimetric variations produced by a binary star placed at the center of an empty spherical cavity inside a circumbinary ellipsoidal and optically thin envelope made of dust grains . Mie single-scattering ( on spherical dust grains ) is considered along with pre- and post-scattering extinction factors which produce a time-varying optical depth and affect the morphology of the periodic variations . The orbits are circular or eccentric . The mass ratio ( and luminosity ratio ) is equal to 1.0 . We are interested in the effects that various parameters ( grain characteristics , geometry of the envelope , orbital eccentricity , etc . ) will have on the average polarization , the amplitude of the polarimetric variations , and the morphology of the variability . We show that the absolute amplitudes of the variations are smaller for Mie scattering than for Thomson scattering , which makes harder the detection of polarimetric variations for binary stars surrounded by dust grains . The average polarization produced depends on the grains ’ composition and size , and on the wavelength of observation . Among the four grain types that we have studied ( astronomical silicates , graphite , amorphous carbon , and dirty ice ) , the highest polarizations are produced by grains with sizes in the range a \sim 0.1 – 0.2 \micron ( x = 2 \pi a / \lambda \sim 1.0 – 2.0 for \lambda = 7000 Å ) . Composition and size also determine if the polarization will be positive or negative . In general , the variations are double-periodic ( seen twice per orbit ) . In some cases , because spherical dust grains have an asymmetric scattering function , the polarimetric curves produced show single-periodic variations ( seen once per orbit ) in addition to the double-periodic ones . A mixture of grains of different sizes does not affect those conclusions . Circumstellar disks produce polarimetric variations of greater amplitude ( up to \sim 0.3 % in our simulations ) than circumbinary envelopes ( usually \lesssim 0.1 % ) . Other geometries ( circumbinary flared disks or prolate envelopes , and non-coplanar envelopes ) do not present particularly interesting polarimetric characteristics . Another goal of these simulations is to see if the 1978 BME ( Brown , McLean , & Emslie ) formalism , which uses a Fourier analysis of the polarimetric variations to find the orbital inclination for Thomson-scattering envelopes , can still be used for Mie scattering . We find that this is the case , if the amplitude of the variations is sufficient and the true inclinations is i _ { true } \gtrsim 45 \arcdeg . For eccentric orbits , the first-order coefficients of the Fourier fit , instead of second-order ones , can be used to find almost all inclinations .